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The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapours of water and toluene, the mole fraction of water X w in the vapour phase satisfies

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  1.  0 < X w < 0.5

  2.  X w = 0.5

  3.  0.5 < X w < 1.0

  4.  X w = 1.0

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